Homoleptic Rh(III)-Diphosphine and Rh(III)-Diarsine Complexes

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Title:Homoleptic Rh(III)-Diphosphine and Rh(III)-Diarsine Complexes
Creators:
Bickley, Jamie
Higgins, Simon J.
La Pensée, Annemarie A.
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 68, 8, pp. 1461-1466
Uncontrolled Keywords:Phosphanes, Multinuclear NMR spectroscopy, Arsanes, Phosphines, Rhodium complexes, Arsines, P ligands, As ligands

Abstract

The first examples of homoleptic diarsine and diphosphine coordination to Rh(III), <i>viz</i>. [Rh(1,2-C<sub>6</sub>H<sub>4</sub>{AsMe<sub>2</sub>}<sub>2</sub>)<sub>3</sub>]<sup>3+</sup> and [Rh(Me<sub>2</sub>PCH<sub>2</sub>PMe<sub>2</sub>)<sub>3</sub>]<sup>3+</sup>, are reported, together with details of their characterisation by multinuclear NMR spectroscopy and mass spectrometry. <p>

Title:Homoleptic Rh(III)-Diphosphine and Rh(III)-Diarsine Complexes
Creators:
Bickley, Jamie
Higgins, Simon J.
La Pensée, Annemarie A.
Uncontrolled Keywords:Phosphanes, Multinuclear NMR spectroscopy, Arsanes, Phosphines, Rhodium complexes, Arsines, P ligands, As ligands
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:68
Number:8
Page Range:pp. 1461-1466
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20031461UNSPECIFIED
ID Code:2131
Item Type:Article
Deposited On:06 Feb 2009 17:15
Last Modified:06 Feb 2009 16:15

Citation

Bickley, Jamie; Higgins, Simon J.; La Pensée, Annemarie A. (2003) Homoleptic Rh(III)-Diphosphine and Rh(III)-Diarsine Complexes. Collection of Czechoslovak Chemical Communications, 68 (8). pp. 1461-1466. ISSN 0010-0765

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