Controlled and Living Polymerizations Induced with Rhodium Catalysts. A Review

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Title:Controlled and Living Polymerizations Induced with Rhodium Catalysts. A Review
Creators:
Sedláček, Jan
Vohlídal, Jiří
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 68, 10, pp. 1745-1790
Uncontrolled Keywords:Mesoporous molecular sieves, Ring-opening polymerization, Cross-dehydrocoupling polymerization, Polyphosphinoboranes, Substituted acetylenes, Polyketones, Ionic liquids, Immobilized catalysts, Mesoporous supports, Hydrosilylative addition copolymerization, Anchored catalysts, Living polymerization, Polyvinylenes, Dehydrocoupling, Rhodium diene complexes, Atom transfer radical polymerization, Helical polymers, Heterophase catalysis, Polyacetylenes, Polysilylenevinylenes

Abstract

In the last fifteen years, a large variety of specialty polymers of diverse chemical structure and functionality have been synthesized with the rhodium-based catalysts. The high tolerance to the reaction medium and functional groups of monomers, as well as ability to control various structure features of the polymer formed are typical properties of these catalysts. In addition, some rhodium catalysts can be anchored to inorganic or organic supports or dissolved in ionic liquids to form heterophase polymerization systems, which opens the way to pure, well-defined polymers free of the catalyst residues, as well as to recycling rhodium catalysts. This review provides a survey on the polymerization reactions induced with rhodium-based catalysts, in which one or more structure attributes of the polymer formed are subject to control. The structure attributes considered are (i) sequential arrangement of monomeric units along polymer chains; (ii) head-tail isomerism of polymer molecules; (iii) configurational structure of polymer molecules; (iv) conformation of polymer molecules; and (v) molecular weight and molecular-weight distribution of the polymer formed. A&nbsp;review with 188 references. <p>

Title:Controlled and Living Polymerizations Induced with Rhodium Catalysts. A Review
Creators:
Sedláček, Jan
Vohlídal, Jiří
Uncontrolled Keywords:Mesoporous molecular sieves, Ring-opening polymerization, Cross-dehydrocoupling polymerization, Polyphosphinoboranes, Substituted acetylenes, Polyketones, Ionic liquids, Immobilized catalysts, Mesoporous supports, Hydrosilylative addition copolymerization, Anchored catalysts, Living polymerization, Polyvinylenes, Dehydrocoupling, Rhodium diene complexes, Atom transfer radical polymerization, Helical polymers, Heterophase catalysis, Polyacetylenes, Polysilylenevinylenes
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:68
Number:10
Page Range:pp. 1745-1790
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20031745UNSPECIFIED
ID Code:2151
Item Type:Article
Deposited On:06 Feb 2009 17:16
Last Modified:06 Feb 2009 16:16

Citation

Sedláček, Jan; Vohlídal, Jiří (2003) Controlled and Living Polymerizations Induced with Rhodium Catalysts. A Review. Collection of Czechoslovak Chemical Communications, 68 (10). pp. 1745-1790. ISSN 0010-0765

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