Photocatalytic Oxidation of Cyclohexene on Titanium(IV) Oxide

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Title:Photocatalytic Oxidation of Cyclohexene on Titanium(IV) Oxide
Creators:
Klisáková, Jana
Klusoň, Petr
Červený, Libor
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 68, 10, pp. 1985-1997
Uncontrolled Keywords:Epoxidation, Heterogeneous catalysis, Cyclohexene, Titania, Photochemical oxidation, Alkenes, Partial oxidation

Abstract

Photocatalytic oxidation of cyclohexene was carried out over a series of titanium(IV) oxide catalysts. These species acting together with molecular oxygen significantly differed in their surface and structural properties. Attention was paid to elimination of the total decomposition of the alkene molecules to water and carbon dioxide and to favour formation of reaction intermediates, comprising epoxide units. Experiments were performed in liquid phase at atmospheric pressure, room temperature and under UV illumination. A quartz reactor was used and the reaction mixture was agitated by oxygen. Significant variations in the reaction selectivity were detected as a function of catalyst structural properties. <p>

Title:Photocatalytic Oxidation of Cyclohexene on Titanium(IV) Oxide
Creators:
Klisáková, Jana
Klusoň, Petr
Červený, Libor
Uncontrolled Keywords:Epoxidation, Heterogeneous catalysis, Cyclohexene, Titania, Photochemical oxidation, Alkenes, Partial oxidation
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:68
Number:10
Page Range:pp. 1985-1997
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20031985UNSPECIFIED
ID Code:2166
Item Type:Article
Deposited On:06 Feb 2009 17:16
Last Modified:06 Feb 2009 16:16

Citation

Klisáková, Jana; Klusoň, Petr; Červený, Libor (2003) Photocatalytic Oxidation of Cyclohexene on Titanium(IV) Oxide. Collection of Czechoslovak Chemical Communications, 68 (10). pp. 1985-1997. ISSN 0010-0765

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