Recent Advances in the Functionalizations of the Upper Rims of Thiacalix[4]arenes. A Review

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Title:Recent Advances in the Functionalizations of the Upper Rims of Thiacalix[4]arenes. A Review
Creators:
Parola, Stephane
Desroches, Cedric
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 69, 5, pp. 966-983
Uncontrolled Keywords:Thioethers, Thiacalixarenes, Calixarenes, Halogenations, Macrocycles, Sulfides, Upper rims, Cross-coupling reactions, Electrophilic substitutions

Abstract

The chemistry of the thiacalixarenes is very recent compared to that of similar calixarenes. Several papers have recently reported interesting progress in the chemistry of thiacalixarenes. Until recently most of the reactions concerned the substitutions of the lower rims while only very few were dealing with the upper rims. Indeed it was shown that the macrocycles often behave in a very different way compared to the similar calixarenes, and the well-known reactions such as nitration, bromination or formylation could not be directly transposed to the thiacalixarenes. However many important intermediates for upper-rim substitution were recently reported and are resumed in this paper together with further functionalizations of the upper rims and potential developments in the chemistry and applications of thiacalixarenes. A review with 40 references. <p>

Title:Recent Advances in the Functionalizations of the Upper Rims of Thiacalix[4]arenes. A Review
Creators:
Parola, Stephane
Desroches, Cedric
Uncontrolled Keywords:Thioethers, Thiacalixarenes, Calixarenes, Halogenations, Macrocycles, Sulfides, Upper rims, Cross-coupling reactions, Electrophilic substitutions
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:69
Number:5
Page Range:pp. 966-983
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20040966UNSPECIFIED
ID Code:2255
Item Type:Article
Deposited On:06 Feb 2009 17:17
Last Modified:06 Feb 2009 16:17

Citation

Parola, Stephane; Desroches, Cedric (2004) Recent Advances in the Functionalizations of the Upper Rims of Thiacalix[4]arenes. A Review. Collection of Czechoslovak Chemical Communications, 69 (5). pp. 966-983. ISSN 0010-0765

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