Exceptionally Symmetric Crystal Structure of (Pentabenzylcyclopentadienyl)(cyclooctatetraene)titanium(III)

[img]PDF - Authorized users only
Language: English
126Kb
Title:Exceptionally Symmetric Crystal Structure of (Pentabenzylcyclopentadienyl)(cyclooctatetraene)titanium(III)
Creators:
Císařová, Ivana
Varga, Vojtech
Horáček, Michal
Kubišta, Jiří
Mach, Karel
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 69, 11, pp. 2036-2044
Uncontrolled Keywords:Titanium, Titanocenes, Conformation analysis, X-Ray diffraction, Sandwich complexes, Cyclooctatetraene, Metallocenes, ESR spectroscopy

Abstract

Complex [Ti(III)(η<sup>8</sup>-C<sub>8</sub>H<sub>8</sub>)(η<sup>5</sup>-C<sub>5</sub>Bn<sub>5</sub>)] (<strong>1</strong>) was prepared by salt metathesis reaction of [TiCl(η<sup>8</sup>-C<sub>8</sub>H<sub>8</sub>)(thf)]<sub>2</sub> with LiC<sub>5</sub>Bn<sub>5</sub> and characterized by ESR and UV-near-IR spectra. Its crystal structure is symmetric with respect to a mirror plane involving the titanium atom and one of the benzyl groups. <p>

Title:Exceptionally Symmetric Crystal Structure of (Pentabenzylcyclopentadienyl)(cyclooctatetraene)titanium(III)
Creators:
Císařová, Ivana
Varga, Vojtech
Horáček, Michal
Kubišta, Jiří
Mach, Karel
Uncontrolled Keywords:Titanium, Titanocenes, Conformation analysis, X-Ray diffraction, Sandwich complexes, Cyclooctatetraene, Metallocenes, ESR spectroscopy
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:69
Number:11
Page Range:pp. 2036-2044
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20042036UNSPECIFIED
ID Code:2318
Item Type:Article
Deposited On:06 Feb 2009 17:17
Last Modified:06 Feb 2009 16:17

Citation

Císařová, Ivana; Varga, Vojtech; Horáček, Michal; Kubišta, Jiří; Mach, Karel (2004) Exceptionally Symmetric Crystal Structure of (Pentabenzylcyclopentadienyl)(cyclooctatetraene)titanium(III). Collection of Czechoslovak Chemical Communications, 69 (11). pp. 2036-2044. ISSN 0010-0765

Repository Staff Only: item control page