Electronegativity and Average Local Ionization Energy

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Title:Electronegativity and Average Local Ionization Energy
Creators:
Politzer, Peter
Murray, Jane S.
Grice, M. Edward
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 70, 5, pp. 550-558
Uncontrolled Keywords:Atomic surfaces, Valence electrons, Electron affinity, Electronegativity, Configuration energy, Ionization potential

Abstract

A variation of an earlier formulation of electronegativity by Allen, as the average valence electron ionization energy of a ground-state atom, is proposed. It is shown that the calculated average local ionization energies on the 0.001 a.u. electronic density contours of atoms correlate very well with Allen's values. Our procedure makes it unnecessary to enumerate valence electrons, which can be a problem due to interpenetration of shells. <p>

Title:Electronegativity and Average Local Ionization Energy
Creators:
Politzer, Peter
Murray, Jane S.
Grice, M. Edward
Uncontrolled Keywords:Atomic surfaces, Valence electrons, Electron affinity, Electronegativity, Configuration energy, Ionization potential
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:70
Number:5
Page Range:pp. 550-558
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20050550UNSPECIFIED
ID Code:2378
Item Type:Article
Deposited On:06 Feb 2009 17:18
Last Modified:06 Feb 2009 16:18

Citation

Politzer, Peter; Murray, Jane S.; Grice, M. Edward (2005) Electronegativity and Average Local Ionization Energy. Collection of Czechoslovak Chemical Communications, 70 (5). pp. 550-558. ISSN 0010-0765

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