Donor-Acceptor Complexes of Sulfur Trioxide with 1,4-Dioxane and Their Crystal Structures

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Title:Donor-Acceptor Complexes of Sulfur Trioxide with 1,4-Dioxane and Their Crystal Structures
Creators:
Richtera, Lukáš
Taraba, Jan
Toužín, Jiří
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 71, 2, pp. 155-163
Uncontrolled Keywords:X-Ray diffraction, Sulfur trioxide, Raman spectroscopy, Crystal engineering, Donor-acceptor complexes, 1,4-Dioxane, Crystal structure

Abstract

Crystal and molecular structure of adducts C<sub>4</sub>H<sub>8</sub>O<sub>2</sub>·SO<sub>3</sub> and C<sub>4</sub>H<sub>8</sub>O<sub>2</sub>·2SO<sub>3</sub> were determined by X-ray structure analysis and Raman spectroscopy. Both compounds crystallize from excess of 1,4-dioxane as solvate C<sub>4</sub>H<sub>8</sub>O<sub>2</sub>·SO<sub>3</sub>·C<sub>4</sub>H<sub>8</sub>O<sub>2</sub>, which was characterized by the same methods. Conditions for preparation of all the three compounds in high purity and good yields were optimized. Solvates C<sub>4</sub>H<sub>8</sub>O<sub>2</sub>·H<sub>2</sub>SO<sub>4</sub> and C<sub>4</sub>H<sub>8</sub>O<sub>2</sub>·H<sub>2</sub>S<sub>2</sub>O<sub>7</sub> were identified among products of self-decomposition of C<sub>4</sub>H<sub>8</sub>O<sub>2</sub>·SO<sub>3</sub> and C<sub>4</sub>H<sub>8</sub>O<sub>2</sub>·2SO<sub>3</sub> in tetrachloromethane solution, respectively. <p>

Title:Donor-Acceptor Complexes of Sulfur Trioxide with 1,4-Dioxane and Their Crystal Structures
Creators:
Richtera, Lukáš
Taraba, Jan
Toužín, Jiří
Uncontrolled Keywords:X-Ray diffraction, Sulfur trioxide, Raman spectroscopy, Crystal engineering, Donor-acceptor complexes, 1,4-Dioxane, Crystal structure
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:71
Number:2
Page Range:pp. 155-163
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20060155UNSPECIFIED
ID Code:2470
Item Type:Article
Deposited On:06 Feb 2009 17:19
Last Modified:06 Feb 2009 16:19

Citation

Richtera, Lukáš; Taraba, Jan; Toužín, Jiří (2006) Donor-Acceptor Complexes of Sulfur Trioxide with 1,4-Dioxane and Their Crystal Structures. Collection of Czechoslovak Chemical Communications, 71 (2). pp. 155-163. ISSN 0010-0765

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