Synthesis of 1-Alkanoyl-1'-(trifluoroacetyl)ferrocenes

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Title:Synthesis of 1-Alkanoyl-1'-(trifluoroacetyl)ferrocenes
Creators:
Sobociková, Marie
Štěpnička, Petr
Ramella, Daniele
Kotora, Martin
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 71, 2, pp. 190-196
Uncontrolled Keywords:Electrochemistry, Fluorous ferrocenes, Sandwich complexes, Acylation, Trifluoroacetylation, Ferrocenes, Metallocenes, Electrophilic substitution

Abstract

Synthesis of the first representatives of mixed acyl(perfluoroacyl)ferrocenes, 1-acetyl-1'-(trifluoroacetyl)ferrocene (<strong>3a</strong>) and 1-propionyl-1'-(trifluoroacetyl)ferrocene (<strong>3b</strong>), by stepwise Friedel-Crafts acylation is described. A comparison of redox potentials of acetylferrocene, (trifluoroacetyl)ferrocene, and <strong>3a</strong> as determined by cyclic voltammetry shows that the substitution effect is not purely additive. <p>

Title:Synthesis of 1-Alkanoyl-1'-(trifluoroacetyl)ferrocenes
Creators:
Sobociková, Marie
Štěpnička, Petr
Ramella, Daniele
Kotora, Martin
Uncontrolled Keywords:Electrochemistry, Fluorous ferrocenes, Sandwich complexes, Acylation, Trifluoroacetylation, Ferrocenes, Metallocenes, Electrophilic substitution
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:71
Number:2
Page Range:pp. 190-196
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc20060190UNSPECIFIED
ID Code:2473
Item Type:Article
Deposited On:06 Feb 2009 17:19
Last Modified:06 Feb 2009 16:19

Citation

Sobociková, Marie; Štěpnička, Petr; Ramella, Daniele; Kotora, Martin (2006) Synthesis of 1-Alkanoyl-1'-(trifluoroacetyl)ferrocenes. Collection of Czechoslovak Chemical Communications, 71 (2). pp. 190-196. ISSN 0010-0765

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