Activity Ratios of Lyate Ions in the Water-Alcohol Mixtures

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Title:Activity Ratios of Lyate Ions in the Water-Alcohol Mixtures
Creators:
Pavelek, Zdeněk
Mollin, Jiří
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 57, 2, pp. 255-262

Abstract

A new method for calculating the activity ratio of lyate ions in the water-alcohol mixtures is proposed on the basis of utilizing the linear relations between the Gibbs energies of ion transfer. The results for the water-methanol, -ethanol, and -2-propanol systems are compared with literature data. At the same time, the individual ionic products of water and alcohol in their mixtures were calculated. The accuracy of the method depends on the accuracy of experimental determination of the Gibbs energies of electrolyte transfer and of ionic products in mixed solvents.

Title:Activity Ratios of Lyate Ions in the Water-Alcohol Mixtures
Creators:
Pavelek, Zdeněk
Mollin, Jiří
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:57
Number:2
Page Range:pp. 255-262
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19920255UNSPECIFIED
ID Code:27
Item Type:Article
Deposited On:06 Feb 2009 16:36
Last Modified:06 Feb 2009 15:36

Citation

Pavelek, Zdeněk; Mollin, Jiří (1992) Activity Ratios of Lyate Ions in the Water-Alcohol Mixtures. Collection of Czechoslovak Chemical Communications, 57 (2). pp. 255-262. ISSN 0010-0765

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