Kinetic Study of the Oxidation of Alcohols with Quaternary Ammonium Permanganates

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Title:Kinetic Study of the Oxidation of Alcohols with Quaternary Ammonium Permanganates
Creators:
Šumichrast, Robert
Holba, Vladislav
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 58, 8, pp. 1777-1781

Abstract

Kinetics of the oxidation of 2-propanol, 1-butanol, and 1-pentanol with tetraalkylammonium permanganates have been investigated as function of temperature. The studied reactions are partly autocatalytic, colloidal manganese dioxide as one of the reaction products has been identified as the autocatalyst.A computerized iterative procedure has been used in order to obtained the rate constants of both non-catalytic and catalytic reaction steps together with the thermodynamic activation parameters.

Title:Kinetic Study of the Oxidation of Alcohols with Quaternary Ammonium Permanganates
Creators:
Šumichrast, Robert
Holba, Vladislav
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:58
Number:8
Page Range:pp. 1777-1781
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19931777UNSPECIFIED
ID Code:294
Item Type:Article
Deposited On:06 Feb 2009 16:59
Last Modified:06 Feb 2009 15:59

Citation

Šumichrast, Robert; Holba, Vladislav (1993) Kinetic Study of the Oxidation of Alcohols with Quaternary Ammonium Permanganates. Collection of Czechoslovak Chemical Communications, 58 (8). pp. 1777-1781. ISSN 0010-0765

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