Preparation and Properties of (1,2-Diaminocyclohexane)dichloroplatinum(II) Complexes Containing cis or trans 1,2-Diaminocyclohexane

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Title:Preparation and Properties of (1,2-Diaminocyclohexane)dichloroplatinum(II) Complexes Containing cis or trans 1,2-Diaminocyclohexane
Creators:
Valigura, Dušan
Vančová, Vlasta
Ondrejovič, Gregor
Kováčová, Jolana
Kiss, František
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 57, 3, pp. 457-462

Abstract

The preparation and properties of (1,2-diaminocyclohexane)dichloroplatinum(II) complexes containing <i>cis</i> and <i>trans</i> 1,2-diaminocyclohexane were studied, and the separation of the isomers from their mixture was investigated. Separation in the form of the nickel(II) complexes was chosen with regard to its efficiency and to the possibility of obtaining directly the corresponding 1,2-diaminocyclohexane hydrochloride. Good quality products were obtained in a yield of more than 90% by reacting 1,2-diaminocyclohexane dihydrochloride with K<sub>2</sub>[PtCl<sub>4</sub>] in aqueous solution, pH ca 10, in dark at room temperature.

Title:Preparation and Properties of (1,2-Diaminocyclohexane)dichloroplatinum(II) Complexes Containing cis or trans 1,2-Diaminocyclohexane
Creators:
Valigura, Dušan
Vančová, Vlasta
Ondrejovič, Gregor
Kováčová, Jolana
Kiss, František
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:57
Number:3
Page Range:pp. 457-462
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19920457UNSPECIFIED
ID Code:38
Item Type:Article
Deposited On:06 Feb 2009 16:38
Last Modified:06 Feb 2009 15:38

Citation

Valigura, Dušan; Vančová, Vlasta; Ondrejovič, Gregor; Kováčová, Jolana; Kiss, František (1992) Preparation and Properties of (1,2-Diaminocyclohexane)dichloroplatinum(II) Complexes Containing cis or trans 1,2-Diaminocyclohexane. Collection of Czechoslovak Chemical Communications, 57 (3). pp. 457-462. ISSN 0010-0765

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