Simulation of Primary Selectivity of Hydrocarbon Pyrolysis

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Title:Simulation of Primary Selectivity of Hydrocarbon Pyrolysis
Creators:
Bělohlav, Zdeněk
Horák, Josef
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 57, 9, pp. 1852-1866

Abstract

The mathematical model is described for the determination of primary selectivity of hydrocarbon pyrolysis, i.e., the determination of proportion of single components in the first generation of products of pyrolysis. The model stems from the radical reaction mechanism. It is assumed that the main influence on the product composition has the chain propagation involving the hydrogen atom transfer, isomerization and breaking the hydrocarbon radical. To determine the rate constants, the kinetic data published in the literature and the data on bond enthalpies in hydrocarbon molecules were employed. The simulation results were compared with the experimental data taken from the literature and with the results of measurements obtained in pyrolysis of two types of naphthas in a pilot-plant reactor.

Title:Simulation of Primary Selectivity of Hydrocarbon Pyrolysis
Creators:
Bělohlav, Zdeněk
Horák, Josef
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:57
Number:9
Page Range:pp. 1852-1866
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19921852UNSPECIFIED
ID Code:3849
Item Type:Article
Deposited On:06 Feb 2009 16:46
Last Modified:06 Feb 2009 15:47

Citation

Bělohlav, Zdeněk; Horák, Josef (1992) Simulation of Primary Selectivity of Hydrocarbon Pyrolysis. Collection of Czechoslovak Chemical Communications, 57 (9). pp. 1852-1866. ISSN 0010-0765

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