Conductance and Viscometric Studies of Some Tetraalkylammonium and Sodium Salts in Acetonitrile-Dimethyl Sulfoxide Mixtures at 35 °C

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Title:Conductance and Viscometric Studies of Some Tetraalkylammonium and Sodium Salts in Acetonitrile-Dimethyl Sulfoxide Mixtures at 35 °C
Creators:
Chauhan, Mohinder S.
Sharma, Kishore C.
Gupta, Sanjay
Chauhan, Suvarcha
Syal, Vijay K.
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 57, 10, pp. 2078-2088

Abstract

Molar conductances and viscosities of Bu<sub>4</sub>NBPh<sub>4</sub>, NaBPh<sub>4</sub> and R<sub>4</sub>NBr (R ethyl, propyl and butyl) at 35 °C in acetonitrile (AN), dimethylsulfoxide (DMSO) and their binary mixtures have been reported. The conductivity data has been analysed by the Shedlovsky conductance equation and viscosity data by the Jones-Dole equation. Resolution of limiting molar conductivity (Λ<sub>0</sub>) and viscosity <i>B</i> coefficient of electrolytes into their ionic components have been achieved by the reference salt method. Viscosity <i>A</i> coefficients have been compared with theoretical <i>A</i><sub>η</sub> coefficients. Derived conductance and viscosity parameters have been discussed in terms of the ion-solvent interaction.

Title:Conductance and Viscometric Studies of Some Tetraalkylammonium and Sodium Salts in Acetonitrile-Dimethyl Sulfoxide Mixtures at 35 °C
Creators:
Chauhan, Mohinder S.
Sharma, Kishore C.
Gupta, Sanjay
Chauhan, Suvarcha
Syal, Vijay K.
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:57
Number:10
Page Range:pp. 2078-2088
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19922078UNSPECIFIED
ID Code:3868
Item Type:Article
Deposited On:06 Feb 2009 16:49
Last Modified:06 Feb 2009 15:51

Citation

Chauhan, Mohinder S.; Sharma, Kishore C.; Gupta, Sanjay; Chauhan, Suvarcha; Syal, Vijay K. (1992) Conductance and Viscometric Studies of Some Tetraalkylammonium and Sodium Salts in Acetonitrile-Dimethyl Sulfoxide Mixtures at 35 °C. Collection of Czechoslovak Chemical Communications, 57 (10). pp. 2078-2088. ISSN 0010-0765

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