Analysis of mixtures of organic volatile compound in water by MIMS. Semiquantitative evaluation of data

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Title:Analysis of mixtures of organic volatile compound in water by MIMS. Semiquantitative evaluation of data
Creators:
Musilová-Kebrlová, Natálie
Janderka, Pavel
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 74, 4, pp. 581-597
Uncontrolled Keywords:Chemometrics, DIP, Mixture analysis, Volatile organic compounds, Direct inlet probe, MIMS, VOC, Membrane introduction mass spectrometry

Abstract

Chemometric analysis of intensities of ion currents measured by MIMS was demonstrated on two mixtures: nonpolar mixture containing benzene–toluene–<i>p</i>-xylene (set I) and polar mixture containing methanol–ethanol–propan-1-ol (set II), both in water solutions. The acquired MIMS data were evaluated off-line using Solver, a tool of Microsoft Excel and then verified by calculation of relative concentrations of components in mixtures. For evaluation we considered the additivity of ion currents coming from fragmentation of components, independent vapor permeation of components through membrane and unimolecular conditions in ion source of MS. By using this evaluation analysis it is possible to determine relative concentrations of organic substances in mixture, which penetrated through the membrane, without any separation. Set I penetrated according to the model analysis and the obtained relative concentrations were in reasonable agreement with the preset values. On the contrary, for set II the agreement of adjusted and calculated relative concentrations was not achieved due to high dielectric permittivity of alcohols.

Title:Analysis of mixtures of organic volatile compound in water by MIMS. Semiquantitative evaluation of data
Creators:
Musilová-Kebrlová, Natálie
Janderka, Pavel
Uncontrolled Keywords:Chemometrics, DIP, Mixture analysis, Volatile organic compounds, Direct inlet probe, MIMS, VOC, Membrane introduction mass spectrometry
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:74
Number:4
Page Range:pp. 581-597
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc2008206UNSPECIFIED
ID Code:4187
Item Type:Article
Deposited On:14 Apr 2009 12:50
Last Modified:14 Apr 2009 10:50

Citation

Musilová-Kebrlová, Natálie; Janderka, Pavel (2009) Analysis of mixtures of organic volatile compound in water by MIMS. Semiquantitative evaluation of data. Collection of Czechoslovak Chemical Communications, 74 (4). pp. 581-597. ISSN 0010-0765

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