A Study of the Use of Solubility Isotherms to Obtain Information about Ion Hydration and Ion Pairing in Concentrated Solutions of Electrolytes

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Title:A Study of the Use of Solubility Isotherms to Obtain Information about Ion Hydration and Ion Pairing in Concentrated Solutions of Electrolytes
Creators:
Eysseltová, Jitka
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 59, 1, pp. 126-137

Abstract

<p>Computational analysis of solubility isotherms in ternary systems consisting of water and two solutes having a common ion was suggested and the respective software was developed. This hydration analysis was applied to model systems NH<sub>4</sub>CNS - NaCNS - H<sub>2</sub>O at 5, 25 and 50 °C and NaX - KX - H<sub>2</sub>O (X = Cl, Br, I) at 25 °C. The results obtained are discussed and the way in which the hydration analysis gives information on ionic processes in saturated electrolyte solutions is demonstrated.

Title:A Study of the Use of Solubility Isotherms to Obtain Information about Ion Hydration and Ion Pairing in Concentrated Solutions of Electrolytes
Creators:
Eysseltová, Jitka
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:59
Number:1
Page Range:pp. 126-137
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19940126UNSPECIFIED
ID Code:425
Item Type:Article
Deposited On:06 Feb 2009 17:00
Last Modified:06 Feb 2009 16:00

Citation

Eysseltová, Jitka (1994) A Study of the Use of Solubility Isotherms to Obtain Information about Ion Hydration and Ion Pairing in Concentrated Solutions of Electrolytes. Collection of Czechoslovak Chemical Communications, 59 (1). pp. 126-137. ISSN 0010-0765

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