The Structure of Bis(isopropylxanthato)nickel(II)

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Title:The Structure of Bis(isopropylxanthato)nickel(II)
Creators:
Trávníček, Zdeněk
Pastorek, Richard
Marek, Jaromír
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 59, 3, pp. 616-619

Abstract

<p>The structure of [Ni(i-PrXa)<sub>2</sub>] (i-Pr = i-C<sub>3</sub>H<sub>7</sub>, Xa = S<sub>2</sub>CO-) was solved by the heavy-atom method and refined anisotropically to <i>R</i> = 0.044 for 985 unique observed reflections. The compound crystallizes in the <i>P2</i><sub>1</sub>/<i>c</i> space group with <i>a</i> = 8.879(2), <i>b</i> = 6.086(1), <i>c</i> = 13.203(3) Å, β = 94.74(3)°, <i>V</i> = 711.0(3) Å<sup>3</sup>, <i>T</i> = 296 K, <i>Z</i> = 2. The molecule contains the NiS<sub>4</sub> chromophore with an approximately planar configuration of the four sulfur atoms around the Ni(II). The Ni atom is located in the centre of symmetry.

Title:The Structure of Bis(isopropylxanthato)nickel(II)
Creators:
Trávníček, Zdeněk
Pastorek, Richard
Marek, Jaromír
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:59
Number:3
Page Range:pp. 616-619
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19940616UNSPECIFIED
ID Code:483
Item Type:Article
Deposited On:06 Feb 2009 17:01
Last Modified:06 Feb 2009 16:01

Citation

Trávníček, Zdeněk; Pastorek, Richard; Marek, Jaromír (1994) The Structure of Bis(isopropylxanthato)nickel(II). Collection of Czechoslovak Chemical Communications, 59 (3). pp. 616-619. ISSN 0010-0765

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