Study of the EE mechanism with adsorption of the intermediate at spherical and planar electrodes following a Langmuir’s isotherm

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Title:Study of the EE mechanism with adsorption of the intermediate at spherical and planar electrodes following a Langmuir’s isotherm
Creators:
Alcaraz, María-Luisa
Gálvez, Jesús
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 56, 1, pp. 60-67

Abstract

The theory for the EE mechanism with adsorption of the intermediate following Langmuir’s isotherm has been developed for the expanding sphere with any power law electrode model. The equations obtained with this model are general and can be applied, for example, to a stationary plane electrode, to a stationary sphere electrode, and to the two models of dropping mercury electrode (DME), expanding plane and expanding sphere. The influence exerted by the sphericity of the electrode on the current-potential (<i>I/E</i>) curves and the characteristics of these curves are discussed.

Title:Study of the EE mechanism with adsorption of the intermediate at spherical and planar electrodes following a Langmuir’s isotherm
Creators:
Alcaraz, María-Luisa
Gálvez, Jesús
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:56
Number:1
Page Range:pp. 60-67
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19910060UNSPECIFIED
ID Code:4923
Item Type:Article
Deposited On:22 Feb 2010 11:26
Last Modified:22 Feb 2010 10:26

Citation

Alcaraz, María-Luisa; Gálvez, Jesús (1991) Study of the EE mechanism with adsorption of the intermediate at spherical and planar electrodes following a Langmuir’s isotherm. Collection of Czechoslovak Chemical Communications, 56 (1). pp. 60-67. ISSN 0010-0765

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