Carbon-13 substituent-induced chemical shifts in benzene derivatives: Substituted anilines

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Title:Carbon-13 substituent-induced chemical shifts in benzene derivatives: Substituted anilines
Creators:
Buděšínský, Miloš
Johnels, Dan
Edlund, Ulf
Exner, Otto
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 56, 2, pp. 368-385

Abstract

Carbon-13 NMR spectra are reported for 59 <i>meta</i>- and <i>para</i>-substituted anilines in deuterochloroform or in its mixture with hexadeuterodimethyl sulphoxide. The substituent-induced chemical shifts (SCS) of ring carbon atoms in position 4 correlate well with dual substituent parameters (DSP). In the remaining positions correlations are not satisfactory with any kind of known substituent constants. There is, however, a close resemblance between SCS in the same position of <i>meta</i>- and <i>para</i>-substituted anilines and even in other series of aromatic compounds.

Title:Carbon-13 substituent-induced chemical shifts in benzene derivatives: Substituted anilines
Creators:
Buděšínský, Miloš
Johnels, Dan
Edlund, Ulf
Exner, Otto
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:56
Number:2
Page Range:pp. 368-385
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19910368UNSPECIFIED
ID Code:4956
Item Type:Article
Deposited On:22 Feb 2010 11:27
Last Modified:22 Feb 2010 10:27

Citation

Buděšínský, Miloš; Johnels, Dan; Edlund, Ulf; Exner, Otto (1991) Carbon-13 substituent-induced chemical shifts in benzene derivatives: Substituted anilines. Collection of Czechoslovak Chemical Communications, 56 (2). pp. 368-385. ISSN 0010-0765

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