Reactivity of triformylmethane. I. Reactions of triformylmethane with selected types of amino compounds

[img]PDF - Authorized users only
Language: English
389Kb
Title:Reactivity of triformylmethane. I. Reactions of triformylmethane with selected types of amino compounds
Creators:
Arnold, Zdeněk
Buděšínský, Miloš
Pánková, Magdalena
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 56, 5, pp. 1019-1031

Abstract

Reactions of triformylmethane with various types of amino compounds were investigated. Besides with ammonia, triformylmethane reacts spontaneously with primary amines, aminoacids and their esters, urea and related compounds including carbamic acid derivatives. Reactions with amides of carboxylic and sulfonic acids require catalysis with Lewis acids. Primary products are aminomethylenemalonaldehyde derivatives <i>IIIa-IIIv</i>. Reactions of triformylmethane with excess of selected primary amines and two secondary amines (dimethylamine and morpholine) were also studied.

Title:Reactivity of triformylmethane. I. Reactions of triformylmethane with selected types of amino compounds
Creators:
Arnold, Zdeněk
Buděšínský, Miloš
Pánková, Magdalena
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:56
Number:5
Page Range:pp. 1019-1031
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19911019UNSPECIFIED
ID Code:5019
Item Type:Article
Deposited On:22 Feb 2010 11:28
Last Modified:22 Feb 2010 10:29

Citation

Arnold, Zdeněk; Buděšínský, Miloš; Pánková, Magdalena (1991) Reactivity of triformylmethane. I. Reactions of triformylmethane with selected types of amino compounds. Collection of Czechoslovak Chemical Communications, 56 (5). pp. 1019-1031. ISSN 0010-0765

Repository Staff Only: item control page