Determination of the intensity of polychromatic radiation in the reaction compartment as a function of wavenumber

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Title:Determination of the intensity of polychromatic radiation in the reaction compartment as a function of wavenumber
Creators:
Hrdina, Radim
Čepčiansky, Igor
Bittová, Hana
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 56, 6, pp. 1173-1179

Abstract

A procedure is suggested for studying the kinetics of photochemical reactions using excitation with polychromatic radiation, where the wavenumber dependence of the intensity of the polychromatic radiation entering the reaction compartment must be known. The observed relative intensities of the polychromatic source are calibrated by ferrioxalate actinometry, selected parts of the emission spectrum being eliminated by insertion of filters. The relative intensities of an HBO 200 high-pressure mercury lamp were measured. For the sake of brevity, the experimental data were fitted by a mathematical model (a polynominal), and only the parameters of the polynomial are presented in a tabular form.

Title:Determination of the intensity of polychromatic radiation in the reaction compartment as a function of wavenumber
Creators:
Hrdina, Radim
Čepčiansky, Igor
Bittová, Hana
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:56
Number:6
Page Range:pp. 1173-1179
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19911173UNSPECIFIED
ID Code:5036
Item Type:Article
Deposited On:22 Feb 2010 11:29
Last Modified:22 Feb 2010 10:29

Citation

Hrdina, Radim; Čepčiansky, Igor; Bittová, Hana (1991) Determination of the intensity of polychromatic radiation in the reaction compartment as a function of wavenumber. Collection of Czechoslovak Chemical Communications, 56 (6). pp. 1173-1179. ISSN 0010-0765

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