The conformation of some trimethylsilylesters by spectroscopic methods

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Title:The conformation of some trimethylsilylesters by spectroscopic methods
Creators:
Al-Azzawi, Souad F.
Jakoubková, Marie
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 56, 6, pp. 1180-1183

Abstract

The doublet structure of <i>v</i>(C=O) bands in the IR absorption spectra of some trimethylsilylesters of carboxylic acids XCOOY [X = CCl<sub>3</sub>, CCl<sub>2</sub>H, CClH<sub>2</sub>, C(CH<sub>3</sub>)<sub>3</sub>, CH<sub>2</sub>Si(CH<sub>3</sub>)<sub>3</sub>] indicates conformational heterogeneity. The conformations of these esters were studied by analyzing the changes in IR spectra caused by solvent and temperature effects.

Title:The conformation of some trimethylsilylesters by spectroscopic methods
Creators:
Al-Azzawi, Souad F.
Jakoubková, Marie
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:56
Number:6
Page Range:pp. 1180-1183
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19911180UNSPECIFIED
ID Code:5037
Item Type:Article
Deposited On:22 Feb 2010 11:29
Last Modified:22 Feb 2010 10:29

Citation

Al-Azzawi, Souad F.; Jakoubková, Marie (1991) The conformation of some trimethylsilylesters by spectroscopic methods. Collection of Czechoslovak Chemical Communications, 56 (6). pp. 1180-1183. ISSN 0010-0765

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