Effect of precipitation and aging on porous structure of aluminium hydroxide. II. Changes in pore size distributions

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Title:Effect of precipitation and aging on porous structure of aluminium hydroxide. II. Changes in pore size distributions
Creators:
Roček, Josef
Pospěch, Roman
Weiss, Jindřich
Jirátová, Květuše
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 56, 6, pp. 1263-1269

Abstract

Differences in porous structure of the dried aluminium hydroxide (containing sulphate ions) caused by changes in temperature and pH of precipitation, the time of aging and by additions of surfactants are documented and discussed. The aluminium hydroxide precipitated at low temperatures (30 – 50°C) and pH values (7 – 8) has bi-disperse porous structure with maxima in the region of large and medium pores. The increase of temperature and pH of precipitation limits or completely suppresses medium pores and increases large and small pores. Characteristic trend was the disappearance of medium pores which led to monodispersity in the region of large and small pores. The addition of surfactants suppressed the effect of short-time aging on pore size distributions. At moderate temperatures the effect of surfactants manifested itself in the broad pore size distributions and in the increase of the volume of large and medium pores. Qualitative and quantitative differences in porous structure caused by the action of surfactants were suppressed on increasing temperature and pH of precipitation.

Title:Effect of precipitation and aging on porous structure of aluminium hydroxide. II. Changes in pore size distributions
Creators:
Roček, Josef
Pospěch, Roman
Weiss, Jindřich
Jirátová, Květuše
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:56
Number:6
Page Range:pp. 1263-1269
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19911263UNSPECIFIED
ID Code:5047
Item Type:Article
Deposited On:22 Feb 2010 11:29
Last Modified:22 Feb 2010 10:29

Citation

Roček, Josef; Pospěch, Roman; Weiss, Jindřich; Jirátová, Květuše (1991) Effect of precipitation and aging on porous structure of aluminium hydroxide. II. Changes in pore size distributions. Collection of Czechoslovak Chemical Communications, 56 (6). pp. 1263-1269. ISSN 0010-0765

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