119Sn and 13C NMR Spectral Study of Some Vinyltin(IV) Compounds Involving the Sn-S Bond

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Title:119Sn and 13C NMR Spectral Study of Some Vinyltin(IV) Compounds Involving the Sn-S Bond
Creators:
Handlíř, Karel
Lyčka, Antonín
Holeček, Jaroslav
Nádvorník, Milan
Pejchal, Vladimír
Sebald, Angelika
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 59, 4, pp. 885-897

Abstract

<p>The <sup>13</sup>C and <sup>119</sup>Sn NMR spectra were examined for two series of vinyltin(IV) compounds involving the Sn-S bond, of general formulas (CH<sub>2</sub>=CH)<i><sub>n</sub></i>Sn(SR)<sub>4 - <i>n</i></sub> (<i>n</i> = 0 - 4) and (CH<sub>2</sub>=CH)<i><sub>n</sub></i>Sn(Cl)(SR)<sub>3 - <i>n</i></sub> (<i>n</i> = 0 - 3) where R = 1-C<sub>4</sub>H<sub>9</sub>, C(S)N(C<sub>2</sub>H<sub>5</sub>)<sub>2</sub> or 8-quinolinyl C<sub>9</sub>H<sub>6</sub>N, or SR = 1/2 (SCH<sub>2</sub>CH<sub>2</sub>S). Deuteriochloroform and hexadeuteriodimethyl sulfoxide served as non-coordinating and coordinating solvents, respectively. The <sup>13</sup>C and <sup>119</sup>Sn NMR data provided a basis for discussion of the nature and strength of the Sn-S bonding, coordination of the central tin atom including the shape of the coordination polyhedron, and the ability of the compounds to form donor acceptor complexes.

Title:119Sn and 13C NMR Spectral Study of Some Vinyltin(IV) Compounds Involving the Sn-S Bond
Creators:
Handlíř, Karel
Lyčka, Antonín
Holeček, Jaroslav
Nádvorník, Milan
Pejchal, Vladimír
Sebald, Angelika
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:59
Number:4
Page Range:pp. 885-897
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19940885UNSPECIFIED
ID Code:508
Item Type:Article
Deposited On:06 Feb 2009 17:01
Last Modified:06 Feb 2009 16:01

Citation

Handlíř, Karel; Lyčka, Antonín; Holeček, Jaroslav; Nádvorník, Milan; Pejchal, Vladimír; Sebald, Angelika (1994) 119Sn and 13C NMR Spectral Study of Some Vinyltin(IV) Compounds Involving the Sn-S Bond. Collection of Czechoslovak Chemical Communications, 59 (4). pp. 885-897. ISSN 0010-0765

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