Structure of a palladium(II) complex with a non-symmetrical tetradentate Schiff base, [Pd(C14H20N3O)]NCS

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Title:Structure of a palladium(II) complex with a non-symmetrical tetradentate Schiff base, [Pd(C14H20N3O)]NCS
Creators:
Kratochvíl, Bohumil
Ondráček, Jan
Maixner, Jaroslav
Macíček, Josef
Haber, Václav
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 56, 9, pp. 1900-1907

Abstract

The structure of (1-phenyl-3-{2-[(2-aminoethyl)amino]ethylimino}-1-buten-1-olato-O,N,N’,N”) palladium(II) thiocyanate, [Pd(baden)]NCS, was solved by heavy-atom method and refined anisotropically ro <i>R</i> = 0.026 for 2 851 unique observed reflections. The title complex crystallizes in the <i>Pc2</i><sub>1</sub><i>b</i> space group with <i>a</i> = 11.919(2), <i>b</i> = 14.061(2), <i>c</i> = 19.769(3)Å, <i>Z</i> = 8. The structure contains two symmetrical-independent molecules, each includes the palladium complex cation and thiocyanate anion. The cation formed by the baden ligand consists of one six-membered and two five-membered chelate rings and the phenyl ring. The coordination polyhedron around palladium is slightly distorted and puckered N<sub>3</sub>O square. The structure is held predominantly by electrostatic forces, but besides there are weak intermolecular hydrogen bonds among baden and thiocyanate nitrogens.

Title:Structure of a palladium(II) complex with a non-symmetrical tetradentate Schiff base, [Pd(C14H20N3O)]NCS
Creators:
Kratochvíl, Bohumil
Ondráček, Jan
Maixner, Jaroslav
Macíček, Josef
Haber, Václav
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:56
Number:9
Page Range:pp. 1900-1907
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19911900UNSPECIFIED
ID Code:5115
Item Type:Article
Deposited On:22 Feb 2010 11:30
Last Modified:22 Feb 2010 10:31

Citation

Kratochvíl, Bohumil; Ondráček, Jan; Maixner, Jaroslav; Macíček, Josef; Haber, Václav (1991) Structure of a palladium(II) complex with a non-symmetrical tetradentate Schiff base, [Pd(C14H20N3O)]NCS. Collection of Czechoslovak Chemical Communications, 56 (9). pp. 1900-1907. ISSN 0010-0765

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