Electroreduction of a benzenediazonium salt in the presence of a radical acceptor

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Title:Electroreduction of a benzenediazonium salt in the presence of a radical acceptor
Creators:
Janderka, Pavel
Zábrš, Leoš
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 56, 10, pp. 2067-2072

Abstract

Potentiostatic reduction of <i>p</i>-methoxybenzenediazoniumtetrafluoroborate was studied in acidic aqueous solutions and in dimethylformamide. The mean number of electrons transferred to a molecule of the depolarizer is influenced by the presence of a radical acceptor, acrylamide, and depends on its concentration. The course of electrolysis in the presence of acrylamide was investigated by measuring the relative viscosity of the electrolysed solution. A polymer was isolated from both aqueous and nonaqueous solutions, and its mean relative molecular mass was determined by viscosimetry in an aqueous solution.

Title:Electroreduction of a benzenediazonium salt in the presence of a radical acceptor
Creators:
Janderka, Pavel
Zábrš, Leoš
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:56
Number:10
Page Range:pp. 2067-2072
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19912067UNSPECIFIED
ID Code:5135
Item Type:Article
Deposited On:22 Feb 2010 11:31
Last Modified:22 Feb 2010 10:31

Citation

Janderka, Pavel; Zábrš, Leoš (1991) Electroreduction of a benzenediazonium salt in the presence of a radical acceptor. Collection of Czechoslovak Chemical Communications, 56 (10). pp. 2067-2072. ISSN 0010-0765

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