Crystal structure of 1,6-anhydro-1(6)-thio-β-D-glucopyranose S-oxide

[img]PDF - Authorized users only
Language: English
202Kb
Title:Crystal structure of 1,6-anhydro-1(6)-thio-β-D-glucopyranose S-oxide
Creators:
Novotný, Jiří
Podlaha, Jaroslav
Černý, Miloslav
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 56, 10, pp. 2169-2174

Abstract

The crystals of the title compound are orthorhombic, space group <i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>, <i>a</i> = 6.193(1), <i>b</i> = 6.3734(7), <i>c</i> = 38.553(6)Å, <i>Z</i> = 8. The structure was solved by direct methods and refined to <i>R</i> = 0.035 for 1 460 independent reflections. It is composed of two crystallographically independent but chemically almost identical molecules. The structure is stabilized by hydrogen bonding characterized by strong participation of the sulfoxide groups. A comparison with the structure of the thio derivative demonstrates that the exo-sulfoxide oxygen influences very little the overall conformation of the bicyclic skeleton.

Title:Crystal structure of 1,6-anhydro-1(6)-thio-β-D-glucopyranose S-oxide
Creators:
Novotný, Jiří
Podlaha, Jaroslav
Černý, Miloslav
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:56
Number:10
Page Range:pp. 2169-2174
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19912169UNSPECIFIED
ID Code:5145
Item Type:Article
Deposited On:22 Feb 2010 11:31
Last Modified:22 Feb 2010 10:31

Citation

Novotný, Jiří; Podlaha, Jaroslav; Černý, Miloslav (1991) Crystal structure of 1,6-anhydro-1(6)-thio-β-D-glucopyranose S-oxide. Collection of Czechoslovak Chemical Communications, 56 (10). pp. 2169-2174. ISSN 0010-0765

Repository Staff Only: item control page