Catalytic conversion of isopropyl alcohol on pure and alkali doped samarium oxide

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Title:Catalytic conversion of isopropyl alcohol on pure and alkali doped samarium oxide
Creators:
Said, Abd El-Aziz Ahmed
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 56, 12, pp. 2807-2814

Abstract

The catalytic conversion of isopropyl alcohol (IPA) on pure and alkali doped Sm<sub>2</sub>O<sub>3</sub> (10 mole %) was studied in flow system. The reaction is mainly dehydration-dehydrogenation of IPA. The results revealed that, the reaction products are strongly affected by the nature of employed carrier gase. The reaction in oxygen showed the highest activity and selectivity compared to other carriers. The doping process caused a significant decrease in the activity and selectivity of Sm<sub>2</sub>O<sub>3</sub> solids. Probable mechanistic routes for the dehydration and dehydrogenation processes are proposed.

Title:Catalytic conversion of isopropyl alcohol on pure and alkali doped samarium oxide
Creators:
Said, Abd El-Aziz Ahmed
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:56
Number:12
Page Range:pp. 2807-2814
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19912807UNSPECIFIED
ID Code:5186
Item Type:Article
Deposited On:22 Feb 2010 11:32
Last Modified:22 Feb 2010 10:32

Citation

Said, Abd El-Aziz Ahmed (1991) Catalytic conversion of isopropyl alcohol on pure and alkali doped samarium oxide. Collection of Czechoslovak Chemical Communications, 56 (12). pp. 2807-2814. ISSN 0010-0765

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