Exact analytical formula for a fifth virial coefficient of a hardsphere mixture at infinite dilution for small diameter ratios
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Title:  Exact analytical formula for a fifth virial coefficient of a hardsphere mixture at infinite dilution for small diameter ratios 

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Journal or Publication Title:  Collection of Czechoslovak Chemical Communications, 75, 2, pp. 165173 

Uncontrolled Keywords:  Hardsphere mixture, Statistical thermodynamics, Virial coefficients 

AbstractA new exact analytical formula for the fifth partial virial coefficient, <i>B</i><sub>5</sub><sup>[1]</sup>, of the additive hardsphere mixture (i.e., for four spheres having diameters of σ<sub>1</sub> and one sphere having a diameter of σ<sub>2</sub>), for small diameter ratios (<i>s</i> = σ<sub>2</sub>/σ<sub>1</sub>), is derived. The derivation method is based on simple geometrical arguments and uses as the only input three first terms in the density expansion of the radial distribution function. Title:  Exact analytical formula for a fifth virial coefficient of a hardsphere mixture at infinite dilution for small diameter ratios 

Creators:  

Uncontrolled Keywords:  Hardsphere mixture, Statistical thermodynamics, Virial coefficients 

Divisions:  Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications 

Journal or Publication Title:  Collection of Czechoslovak Chemical Communications 

Volume:  75 

Number:  2 

Page Range:  pp. 165173 

EISSN:  12126950 

Publisher:  Institute of Organic Chemistry and Biochemistry 

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ID Code:  5235 

Item Type:  Article 

Deposited On:  08 Mar 2010 12:31 

Last Modified:  08 Mar 2010 11:31 

CitationLabík, Stanislav (2010) Exact analytical formula for a fifth virial coefficient of a hardsphere mixture at infinite dilution for small diameter ratios. Collection of Czechoslovak Chemical Communications, 75 (2). pp. 165173.Repository Staff Only: item control page
