The Influence of Some Reaction Conditions on the Course of the Electrolytic Preparation of Ammonium Peroxodisulfate

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Title:The Influence of Some Reaction Conditions on the Course of the Electrolytic Preparation of Ammonium Peroxodisulfate
Creators:
Balej, Jan
Thumová, Milada
Špalková, Hana
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 59, 7, pp. 1606-1615

Abstract

<p>As a continuation of the previous paper, the results of the examination on the influence of further operating parameters (anodic current density, anodic current concentration, molar ratio of the starting solutions, <i>P</i><sub>0</sub> = <i>m</i><sup>0</sup>[H<sub>2</sub>SO<sub>4</sub>] / <i>m</i><sup>0</sup>[(NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub>], conversion degree, <i>a</i> = <i>m</i>[(NH<sub>4</sub>)<sub>2</sub>S<sub>2</sub>O<sub>8</sub>] / <i>m</i><sup>0</sup>[(NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub>], composition and form of the anodic material, nature and concentration of anodic additives) on the anodic current efficiency χ and cell voltage of the laboratory flow-through integral electrolyzer model of the monopolar type were presented and discussed. The obtained results may be used for the optimization of the operating conditions of the industrial persulfate electrolyzer of the monopolar as well as bipolar type, too.

Title:The Influence of Some Reaction Conditions on the Course of the Electrolytic Preparation of Ammonium Peroxodisulfate
Creators:
Balej, Jan
Thumová, Milada
Špalková, Hana
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:59
Number:7
Page Range:pp. 1606-1615
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19941606UNSPECIFIED
ID Code:582
Item Type:Article
Deposited On:06 Feb 2009 17:02
Last Modified:06 Feb 2009 16:02

Citation

Balej, Jan; Thumová, Milada; Špalková, Hana (1994) The Influence of Some Reaction Conditions on the Course of the Electrolytic Preparation of Ammonium Peroxodisulfate. Collection of Czechoslovak Chemical Communications, 59 (7). pp. 1606-1615. ISSN 0010-0765

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