Radical Additions of Tertiary Amines to Chlorotrifluoroethylene

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Title:Radical Additions of Tertiary Amines to Chlorotrifluoroethylene
Creators:
Bárta, Milan
Hampl, František
Liška, František
Dědek, Václav
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 59, 8, pp. 1820-1832

Abstract

<p>Radical addition of ethyldimethylamine, cyclohexyldimethylamine, 1-methylpyrrolidine, 1-methylpiperidine, 1-methylperhydroazepine and 1-methylmorpholine to chlorotrifluoroethylene afforded 1 : 1 and 1 : 2 adducts containing 2-chloro-1,1,2-trifluoroethyl groups in the α- or α,α'-positions. Further reaction products were 1 : 2 telomers and secondary products arising by reduction of the chlorine atom in CHFCl groups by tertiary amines. The reaction course and mass and NMR spectra of the products are discussed.

Title:Radical Additions of Tertiary Amines to Chlorotrifluoroethylene
Creators:
Bárta, Milan
Hampl, František
Liška, František
Dědek, Václav
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:59
Number:8
Page Range:pp. 1820-1832
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19941820UNSPECIFIED
ID Code:606
Item Type:Article
Deposited On:06 Feb 2009 17:02
Last Modified:06 Feb 2009 16:02

Citation

Bárta, Milan; Hampl, František; Liška, František; Dědek, Václav (1994) Radical Additions of Tertiary Amines to Chlorotrifluoroethylene. Collection of Czechoslovak Chemical Communications, 59 (8). pp. 1820-1832. ISSN 0010-0765

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