The first metallacarborane triple-decker complexes with a bridging pentaphospholyl ligand

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Title:The first metallacarborane triple-decker complexes with a bridging pentaphospholyl ligand
Creators:
Loginov, Dmitry A.
Vinogradov, Mikhail M.
Starikova, Zoya A.
Petrovskii, Pavel V.
Holub, Josef
Kudinov, Alexander R.
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 75, 9, pp. 981-993
Uncontrolled Keywords:Triple-decker complexes, Metallacarboranes, Boranes, Sandwich compounds, Iron

Abstract

Visible light irradiation of cations [(Carb)Fe(η-C<sub>6</sub>H<sub>6</sub>)]<sup>+</sup> in the presence of Cp*Fe(η-<i>cyclo</i>-P5) affords the μ-pentaphospholyl triple-decker complexes [(Carb)Fe(μ-η:η-<i>cyclo</i>-P<sub>5</sub>)FeCp*]<sup>+</sup> (Carb = 9-SMe2-7,8-C<sub>2</sub>B<sub>9</sub>H<sub>10</sub> (<b>3a</b>) and 1-<i>t</i>-BuNH-1,7,9-C<sub>3</sub>B<sub>8</sub>H<sub>10</sub> (<b>3b</b>)). Structures of <b>3a</b>- and <b>3b</b>[Co(η-7,8-C<sub>2</sub>B<sub>9</sub>H<sub>11</sub>)<sub>2</sub>] were determined by X-ray diffraction. Bonding in <b>3a</b>, <b>3b</b> and mononuclear building blocks was analyzed by energy decomposition analysis.

Title:The first metallacarborane triple-decker complexes with a bridging pentaphospholyl ligand
Creators:
Loginov, Dmitry A.
Vinogradov, Mikhail M.
Starikova, Zoya A.
Petrovskii, Pavel V.
Holub, Josef
Kudinov, Alexander R.
Uncontrolled Keywords:Triple-decker complexes, Metallacarboranes, Boranes, Sandwich compounds, Iron
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:75
Number:9
Page Range:pp. 981-993
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc2010052UNSPECIFIED
ID Code:6204
Item Type:Article
Deposited On:11 Oct 2010 15:44
Last Modified:11 Oct 2010 13:44

Citation

Loginov, Dmitry A.; Vinogradov, Mikhail M.; Starikova, Zoya A.; Petrovskii, Pavel V.; Holub, Josef; Kudinov, Alexander R. (2010) The first metallacarborane triple-decker complexes with a bridging pentaphospholyl ligand. Collection of Czechoslovak Chemical Communications, 75 (9). pp. 981-993.

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