Studies of the Reaction of Triaminophosphines with α,β-Unsaturated Nitriles

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Title:Studies of the Reaction of Triaminophosphines with α,β-Unsaturated Nitriles
Creators:
Hennawy, Ibtisam T.
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 59, 9, pp. 2109-2115

Abstract

<p>Tris(dialkylamino)phosphines <i>IIIa</i> and <i>IIIb</i> react with furfurylidenemalonitrile (<i>Ia</i>) and its thiophene analogue Ib to give a mixture of 1 : 1 adducts <i>IV</i> and <i>V</i>. Compounds <i>IV</i> have aminophosphonium dipolar ion structure, while compounds <i>V</i> are the ylide forms. The ratio of the products depends on the reaction conditions. Some reactions of <i>IV</i> and <i>V</i> are described.

Title:Studies of the Reaction of Triaminophosphines with α,β-Unsaturated Nitriles
Creators:
Hennawy, Ibtisam T.
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:59
Number:9
Page Range:pp. 2109-2115
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19942109UNSPECIFIED
ID Code:635
Item Type:Article
Deposited On:06 Feb 2009 17:02
Last Modified:06 Feb 2009 16:02

Citation

Hennawy, Ibtisam T. (1994) Studies of the Reaction of Triaminophosphines with α,β-Unsaturated Nitriles. Collection of Czechoslovak Chemical Communications, 59 (9). pp. 2109-2115. ISSN 0010-0765

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