Kinetics and Mechanism of Reaction of 2,4-Dinitrobenzaldehyde with Hydroxide Ion

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Title:Kinetics and Mechanism of Reaction of 2,4-Dinitrobenzaldehyde with Hydroxide Ion
Creators:
Macháček, Vladimír
Manová, Jana
Sedlák, Miloš
Štěrba, Vojeslav
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 59, 10, pp. 2262-2268

Abstract

<p>The reaction of 2,4-dinitrobenzaldehyde with hydroxide ion in water is first order in the substrate. The reaction order in hydroxide ion varies from one to two at lower and higher OH<sup>-</sup> concentrations, respectively. The reaction mechanism has been suggested, the p<i>K</i><sub>a</sub> value of reaction product 2-nitro-4-nitrosophenol and the equilibrium constant of formation of the Meisenheimer adduct from 2-nitro-4-nitrosophenoxide and hydroxide ion have been determined.

Title:Kinetics and Mechanism of Reaction of 2,4-Dinitrobenzaldehyde with Hydroxide Ion
Creators:
Macháček, Vladimír
Manová, Jana
Sedlák, Miloš
Štěrba, Vojeslav
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:59
Number:10
Page Range:pp. 2262-2268
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19942262UNSPECIFIED
ID Code:648
Item Type:Article
Deposited On:06 Feb 2009 17:02
Last Modified:06 Feb 2009 16:02

Citation

Macháček, Vladimír; Manová, Jana; Sedlák, Miloš; Štěrba, Vojeslav (1994) Kinetics and Mechanism of Reaction of 2,4-Dinitrobenzaldehyde with Hydroxide Ion. Collection of Czechoslovak Chemical Communications, 59 (10). pp. 2262-2268. ISSN 0010-0765

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