Preparation of β-D-Glucopyranosyl Derivatives of 1,6:2,3- and 1,6:3,4-Dianhydro-β-D-hexopyranoses and Their 1H and 13C NMR Spectra

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Title:Preparation of β-D-Glucopyranosyl Derivatives of 1,6:2,3- and 1,6:3,4-Dianhydro-β-D-hexopyranoses and Their 1H and 13C NMR Spectra
Creators:
Buděšínský, Miloš
Černý, Miloslav
Černý, Ivan
Sámek, Stanislav
Trnka, Tomáš
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 60, 2, pp. 311-323

Abstract

<p>The corresponding acetylated and free 2-O- and 4-O-glucosyl derivatives of dianhydrohexoses Ib - VIIb and Ic - VIIc have been obtained by the reactions of 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide (<i>IX</i>) with 1,6:3,4- and 1,6:2,3-dianhydro-β-D-hexopyranoses (<i>Ia</i> - <i>VIIa</i>). Structure of the products and the effects of glycosylation upon chemical shifts and conformations of the disaccharides prepared have been studied using <sup>1</sup>H and <sup>13</sup>C NMR spectra.

Title:Preparation of β-D-Glucopyranosyl Derivatives of 1,6:2,3- and 1,6:3,4-Dianhydro-β-D-hexopyranoses and Their 1H and 13C NMR Spectra
Creators:
Buděšínský, Miloš
Černý, Miloslav
Černý, Ivan
Sámek, Stanislav
Trnka, Tomáš
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:60
Number:2
Page Range:pp. 311-323
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19950311UNSPECIFIED
ID Code:718
Item Type:Article
Deposited On:06 Feb 2009 17:03
Last Modified:06 Feb 2009 16:03

Citation

Buděšínský, Miloš; Černý, Miloslav; Černý, Ivan; Sámek, Stanislav; Trnka, Tomáš (1995) Preparation of β-D-Glucopyranosyl Derivatives of 1,6:2,3- and 1,6:3,4-Dianhydro-β-D-hexopyranoses and Their 1H and 13C NMR Spectra. Collection of Czechoslovak Chemical Communications, 60 (2). pp. 311-323. ISSN 0010-0765

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