Spectrophotometric Study of the Formation of Iron(III) Complexes with Some Salicylic Acid Derivatives

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Title:Spectrophotometric Study of the Formation of Iron(III) Complexes with Some Salicylic Acid Derivatives
Creators:
Surányi, Terézia M.
Djurendić, Evgenija A.
Vastag, Gyöngyi Gy.
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 60, 3, pp. 464-472

Abstract

<p>The stoichiometric ratio and stability constants of iron(III) complexes with 1,<i>n</i>-di-<i>O</i>-salicyloylalkane-1,<i>n</i>-diols (<i>n</i> = 2 - 8) and <i>N</i>,<i>N</i>'-disalicyloyl-1,<i>n</i>-alkanediamines (<i>n</i>= 2 - 4) were determined spectrophotometrically. In 61.10% aqueous ethanol, the iron-to-ligand ratio is 1 : 1 (FeL<sup>+</sup>). The stability constants of the complexes were measured at 298 K and μ = 0.5 mol dm<sup>-3</sup> (LiCl). Since the determination was performed in a glycinate buffer, the constants were corrected for the side reaction of iron(III) with glycine.

Title:Spectrophotometric Study of the Formation of Iron(III) Complexes with Some Salicylic Acid Derivatives
Creators:
Surányi, Terézia M.
Djurendić, Evgenija A.
Vastag, Gyöngyi Gy.
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:60
Number:3
Page Range:pp. 464-472
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19950464UNSPECIFIED
ID Code:732
Item Type:Article
Deposited On:06 Feb 2009 17:03
Last Modified:06 Feb 2009 16:03

Citation

Surányi, Terézia M.; Djurendić, Evgenija A.; Vastag, Gyöngyi Gy. (1995) Spectrophotometric Study of the Formation of Iron(III) Complexes with Some Salicylic Acid Derivatives. Collection of Czechoslovak Chemical Communications, 60 (3). pp. 464-472. ISSN 0010-0765

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