Hydration of Cyclohexene Catalyzed by Zeolites

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Title:Hydration of Cyclohexene Catalyzed by Zeolites
Creators:
Kučera, Milan
Králik, Milan
Maťaš, Michal
Hudec, Pavol
Hronec, Milan
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 60, 3, pp. 498-504

Abstract

<p>Liquid phase hydration of cyclohexene over faujasite, mordenite and ZSM-5 catalysts at 10 MPa and temperatures 150 - 210 °C in a batch system was studied. Influence of the type and Si/Al ratio of the zeolite on the conversion of cyclohexene and the selectivity to cyclohexanol formation was determined. Performance of the catalyst was also investigated through adsorption measurements of water and cyclohexene. Mordenite with the Si/Al ratio 70 provided the best results. The selectivity to cyclohexanol was 99% at the conversion of cyclohexene 27% at 200 °C after 4 h. All the catalysts were regenerated by calcination at 450 °C.

Title:Hydration of Cyclohexene Catalyzed by Zeolites
Creators:
Kučera, Milan
Králik, Milan
Maťaš, Michal
Hudec, Pavol
Hronec, Milan
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:60
Number:3
Page Range:pp. 498-504
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19950498UNSPECIFIED
ID Code:736
Item Type:Article
Deposited On:06 Feb 2009 17:03
Last Modified:06 Feb 2009 16:03

Citation

Kučera, Milan; Králik, Milan; Maťaš, Michal; Hudec, Pavol; Hronec, Milan (1995) Hydration of Cyclohexene Catalyzed by Zeolites. Collection of Czechoslovak Chemical Communications, 60 (3). pp. 498-504. ISSN 0010-0765

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