Synthesis and Allylic Oxidation of 2,3-Dehydro-9β-benzoyloxy-β-agarofuran

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Title:Synthesis and Allylic Oxidation of 2,3-Dehydro-9β-benzoyloxy-β-agarofuran
Creators:
Chen, Xin
Nan, Fajun
Xiong, Zhaoming
Shao, Sichang
Li, Tongshuang
li, Yulin
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 60, 3, pp. 521-526

Abstract

<p>2,3-Dehydro-9β-benzoyloxy-β-agarofuran (<i>VI</i>), possible precursor of (+/-)-triptogelin G-2 (<i>I</i>), has been synthesized through a twelve-step procedure, allylic oxidation of which with various oxidative reagents has also been investigated, and three unusual oxidized products, ketoaldehyde <i>X</i>, peroxide <i>XI</i>, and ketone <i>XII</i>, were isolated.

Title:Synthesis and Allylic Oxidation of 2,3-Dehydro-9β-benzoyloxy-β-agarofuran
Creators:
Chen, Xin
Nan, Fajun
Xiong, Zhaoming
Shao, Sichang
Li, Tongshuang
li, Yulin
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:60
Number:3
Page Range:pp. 521-526
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19950521UNSPECIFIED
ID Code:739
Item Type:Article
Deposited On:06 Feb 2009 17:03
Last Modified:06 Feb 2009 16:03

Citation

Chen, Xin; Nan, Fajun; Xiong, Zhaoming; Shao, Sichang; Li, Tongshuang; li, Yulin (1995) Synthesis and Allylic Oxidation of 2,3-Dehydro-9β-benzoyloxy-β-agarofuran. Collection of Czechoslovak Chemical Communications, 60 (3). pp. 521-526. ISSN 0010-0765

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