Preparation of Dimethyl Carbonate from Methanol and Carbon Dioxide in the Presence of Sn(IV) and Ti(IV) Alkoxides and Metal Acetates

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Title:Preparation of Dimethyl Carbonate from Methanol and Carbon Dioxide in the Presence of Sn(IV) and Ti(IV) Alkoxides and Metal Acetates
Creators:
Kizlink, Juraj
Pastucha, Ivan
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 60, 4, pp. 687-692

Abstract

<p>The synthesis of dimethyl carbonate by the reaction of methanol with carbon dioxide in the presence of metal alkoxides and metal carboxylates was studied. The best results have been achieved with Ti(IV) and Sn(IV) alkoxides which at 130 to 180 °C and low CO<sub>2</sub> pressures yield dimethyl carbonate in 30 to 100 mole % or 40 to 130 mole % yields with respect to the metal alkoxides, depending on the carbon dioxide (gaseous and solid one, respectively). The yields can be further increased up to 70 - 190 mole % and 90 - 270 mole %, respectively, by the use of chemical scavengers of the reaction water.

Title:Preparation of Dimethyl Carbonate from Methanol and Carbon Dioxide in the Presence of Sn(IV) and Ti(IV) Alkoxides and Metal Acetates
Creators:
Kizlink, Juraj
Pastucha, Ivan
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:60
Number:4
Page Range:pp. 687-692
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19950687UNSPECIFIED
ID Code:757
Item Type:Article
Deposited On:06 Feb 2009 17:03
Last Modified:06 Feb 2009 16:03

Citation

Kizlink, Juraj; Pastucha, Ivan (1995) Preparation of Dimethyl Carbonate from Methanol and Carbon Dioxide in the Presence of Sn(IV) and Ti(IV) Alkoxides and Metal Acetates. Collection of Czechoslovak Chemical Communications, 60 (4). pp. 687-692. ISSN 0010-0765

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