The (η-1,7'-2,2')4,8'-8,4'-(Bis-μ-o-phenylene)bisdicarbollidocobalt(1-)ate Ion [3-Co-4,8'-8,4'(o-C6H4)2(1,2-C2B9H9)2](-). The First Doubly Bridged Metallacarborane Complex. Synthesis, Properties and Structure

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Title:The (η-1,7'-2,2')4,8'-8,4'-(Bis-μ-o-phenylene)bisdicarbollidocobalt(1-)ate Ion [3-Co-4,8'-8,4'(o-C6H4)2(1,2-C2B9H9)2](-). The First Doubly Bridged Metallacarborane Complex. Synthesis, Properties and Structure
Creators:
Plešek, Jaromír
Heřmánek, Stanislav
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 60, 8, pp. 1297-1302

Abstract

<p>The first cobaltacarborane sandwich complex [3-Co-4,8'-8,4'(<i>o</i>-C<sub>6</sub>H<sub>4</sub>)<sub>2</sub>(1,2-C<sub>2</sub>B<sub>9</sub>H<sub>9</sub>)<sub>2</sub>]<sup>(-)</sup> with two <i>o</i>-phenylene bridges between both deltahedral ligands is described. Phenylene rings containing angle of 72 grad bind the Cs counter-ion probably via π-donation. This is why the solubility of Cs salt in water is extremely low. Synthesis, properties and structure of the Cs salt are described.

Title:The (η-1,7'-2,2')4,8'-8,4'-(Bis-μ-o-phenylene)bisdicarbollidocobalt(1-)ate Ion [3-Co-4,8'-8,4'(o-C6H4)2(1,2-C2B9H9)2](-). The First Doubly Bridged Metallacarborane Complex. Synthesis, Properties and Structure
Creators:
Plešek, Jaromír
Heřmánek, Stanislav
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:60
Number:8
Page Range:pp. 1297-1302
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19951297UNSPECIFIED
ID Code:826
Item Type:Article
Deposited On:06 Feb 2009 17:04
Last Modified:06 Feb 2009 16:04

Citation

Plešek, Jaromír; Heřmánek, Stanislav (1995) The (η-1,7'-2,2')4,8'-8,4'-(Bis-μ-o-phenylene)bisdicarbollidocobalt(1-)ate Ion [3-Co-4,8'-8,4'(o-C6H4)2(1,2-C2B9H9)2](-). The First Doubly Bridged Metallacarborane Complex. Synthesis, Properties and Structure. Collection of Czechoslovak Chemical Communications, 60 (8). pp. 1297-1302. ISSN 0010-0765

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