Effect of Triton X100 on Tetramethylammonium Ion Transport Kinetics Through the Water/Nitrobenzene Interface

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Title:Effect of Triton X100 on Tetramethylammonium Ion Transport Kinetics Through the Water/Nitrobenzene Interface
Creators:
Wawrzynczak, Wojciech S.
Figaszewski, Zbigniew
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 60, 9, pp. 1435-1447

Abstract

<p>The tetramethylammonium cation (TMA<sup>+</sup>) transport through the water/nitrobenzene interface modified by the Triton X100 (TX100) adsorption has been investigated using cyclic voltammetry and interfacial tension measurements. Obtained results indicate the strong adsorption of TX100 and its responsible effect on the TMA<sup>+</sup> ion transfer. Adsorption data have been fitted to six theoretical adsorption isotherm equations with the best fitting for the Frumkin isotherm. The mechanism of facilitating effect of TX100 on the TMA<sup>+</sup> transfer has been proposed. The suggested mechanism is different from that developed by other authors.

Title:Effect of Triton X100 on Tetramethylammonium Ion Transport Kinetics Through the Water/Nitrobenzene Interface
Creators:
Wawrzynczak, Wojciech S.
Figaszewski, Zbigniew
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:60
Number:9
Page Range:pp. 1435-1447
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19951435UNSPECIFIED
ID Code:841
Item Type:Article
Deposited On:06 Feb 2009 17:04
Last Modified:06 Feb 2009 16:04

Citation

Wawrzynczak, Wojciech S.; Figaszewski, Zbigniew (1995) Effect of Triton X100 on Tetramethylammonium Ion Transport Kinetics Through the Water/Nitrobenzene Interface. Collection of Czechoslovak Chemical Communications, 60 (9). pp. 1435-1447. ISSN 0010-0765

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