Excess Volume of Mixtures of Oxaalkanes and Branched Alkanes

[img]PDF - Authorized users only
Language: English
56Kb
Title:Excess Volume of Mixtures of Oxaalkanes and Branched Alkanes
Creators:
Trejo, Luis Miguel
Costas, Miguel
Andreoli-Ball, Lina
Patterson, Donald
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 60, 10, pp. 1634-1640

Abstract

<p>Equimolar values of the excess volume, <i>V</i><sup>E</sup>, have been obtained at 25 °C for a series of oxaalkanes, 2,5-dioxahexane, 2,5,8-trioxanonane, 2,5,8,11-tetraoxadodecane, and 2,5,8,11,14-pentaoxapentadecane, mixed with a series of highly-branched alkanes: 2,2-dimethylbutane, 2,2,4-trimethylpentane, 2,2,4,6,6-pentamethylheptane, and 2,2,4,4,6,8,8-heptamethylnonane. The Prigogine-Flory thermodynamic theory predicts the large variations of <i>V</i><sup>E</sup> with the chain-lengths of the molecules in the two series.

Title:Excess Volume of Mixtures of Oxaalkanes and Branched Alkanes
Creators:
Trejo, Luis Miguel
Costas, Miguel
Andreoli-Ball, Lina
Patterson, Donald
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:60
Number:10
Page Range:pp. 1634-1640
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19951634UNSPECIFIED
ID Code:858
Item Type:Article
Deposited On:06 Feb 2009 17:04
Last Modified:06 Feb 2009 16:04

Citation

Trejo, Luis Miguel; Costas, Miguel; Andreoli-Ball, Lina; Patterson, Donald (1995) Excess Volume of Mixtures of Oxaalkanes and Branched Alkanes. Collection of Czechoslovak Chemical Communications, 60 (10). pp. 1634-1640. ISSN 0010-0765

Repository Staff Only: item control page