The First Examples of Metallatricarbollides. Isomeric Twelve-Vertex Cyclopentadienyl Ferratricarbadodecaboranes [(η5-C5H5)-closo-FeC3B8H11]

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Title:The First Examples of Metallatricarbollides. Isomeric Twelve-Vertex Cyclopentadienyl Ferratricarbadodecaboranes [(η5-C5H5)-closo-FeC3B8H11]
Creators:
Štíbr, Bohumil
Holub, Josef
Teixidor, Francesc
Viñas, Clara
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 60, 12, pp. 2023-2027

Abstract

<p>The first metallatricarbollides, six isomeric twelve-vertex metallatricarbaboranes of general structure [(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)-<i>closo</i>-FeC<sub>3</sub>B<sub>8</sub>H<sub>11</sub>], are formed in the reaction between TI[<i>nido</i>-7,8,9-C<sub>3</sub>B<sub>8</sub>H<sub>11</sub>] and [(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)- Fe(CO)<sub>2</sub>I] in toluene at reflux. Two of them have so far been satisfactorily identified as [3-(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)-<i>closo</i>-3,1,2,4-FeC<sub>3</sub>B<sub>8</sub>H<sub>11</sub>] and [2-(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)-<i>closo</i>-2,1,8,11-FeC<sub>3</sub>B<sub>8</sub>H<sub>11</sub>] by NMR spectroscopy.

Title:The First Examples of Metallatricarbollides. Isomeric Twelve-Vertex Cyclopentadienyl Ferratricarbadodecaboranes [(η5-C5H5)-closo-FeC3B8H11]
Creators:
Štíbr, Bohumil
Holub, Josef
Teixidor, Francesc
Viñas, Clara
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:60
Number:12
Page Range:pp. 2023-2027
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19952023UNSPECIFIED
ID Code:888
Item Type:Article
Deposited On:06 Feb 2009 17:04
Last Modified:06 Feb 2009 16:04

Citation

Štíbr, Bohumil; Holub, Josef; Teixidor, Francesc; Viñas, Clara (1995) The First Examples of Metallatricarbollides. Isomeric Twelve-Vertex Cyclopentadienyl Ferratricarbadodecaboranes [(η5-C5H5)-closo-FeC3B8H11]. Collection of Czechoslovak Chemical Communications, 60 (12). pp. 2023-2027. ISSN 0010-0765

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