Assignment of Nitrogen Stereochemistry of Agroclavine and Elymoclavine 6-N-Oxides

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Title:Assignment of Nitrogen Stereochemistry of Agroclavine and Elymoclavine 6-N-Oxides
Creators:
Křen, Vladimír
Němeček, Jan
Přikrylová, Věra
Journal or Publication Title:
Collection of Czechoslovak Chemical Communications, 60, 12, pp. 2165-2169

Abstract

<p>Both possible 6-N-oxides of agroclavine (I) and elymoclavine (II) were prepared by hydrogen peroxide oxidation. Their <sup>1</sup>H and <sup>13</sup>C NMR spectra were assigned and the conformation of the D ring (half-chair) was determined. Absolute configuration at 6-N was established by NMR and molecular modelling.

Title:Assignment of Nitrogen Stereochemistry of Agroclavine and Elymoclavine 6-N-Oxides
Creators:
Křen, Vladimír
Němeček, Jan
Přikrylová, Věra
Divisions:Life and Chemical Sciences > Institute of Organic Chemistry and Biochemistry > Collection of Czechoslovak Chemical Communications
Journal or Publication Title:Collection of Czechoslovak Chemical Communications
Volume:60
Number:12
Page Range:pp. 2165-2169
ISSN:0010-0765
E-ISSN:1212-6950
Publisher:Institute of Organic Chemistry and Biochemistry
Related URLs:
URLURL Type
http://dx.doi.org/10.1135/cccc19952165UNSPECIFIED
ID Code:905
Item Type:Article
Deposited On:06 Feb 2009 17:04
Last Modified:06 Feb 2009 16:05

Citation

Křen, Vladimír; Němeček, Jan; Přikrylová, Věra (1995) Assignment of Nitrogen Stereochemistry of Agroclavine and Elymoclavine 6-N-Oxides. Collection of Czechoslovak Chemical Communications, 60 (12). pp. 2165-2169. ISSN 0010-0765

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